Tuesday, January 4, 2011

GREEN SOLUTIONS FOR ENERGY CRISIS-METHANOL


Methanol economy


The methanol economy is a suggested future economy in which methanol replaces fossil fuels as a means of energy storage, fuel and raw material for synthetic hydrocarbons and their products. It offers an alternative to the proposed hydrogen economy or ethanol economy.
Since the 1990s Nobel prize winner George A. Olah started to advocate the methanol economy [1][2][3] and in 2006 he and two co-authors (G.K. Surya Prakash and Alain Goeppert) published a book around this theme [4]. In these publications, they summarize the state of our fossil fuel and alternative energy sources, their availability and limitations before suggesting a new approach in the so called methanol economy.
Methanol is a fuel for heat engines and fuel cells. Due to its high octane rating it can be used directly as a fuel in flex-fuel cars (including hybrid and plug-in hybridvehicles) using existing internal combustion engines (ICE). Methanol can also be used as a fuel in fuel cells, either directly in Direct Methanol Fuel Cells (DMFC) or indirectly after conversion into hydrogen by reforming.
Methanol is a liquid under normal conditions, allowing it to be stored, transported and dispensed easily, much like gasoline and diesel fuel is currently. It can also be readily transformed by dehydration into dimethyl ether, a diesel fuel substitute with a cetane number of 55.
Methanol is already used today on a large scale (about 37 million tonnes per year)[5] as a raw material to produce numerous chemical products and materials. In addition, it can be readily converted in the methanol to olefin (MTO) process into ethylene and propylene, which can be used to produce synthetic hydrocarbons and their products, currently obtained from oil and natural gas.
Methanol can be efficiently produced from a wide variety of sources including still abundant fossil fuels (natural gas, coal, oil shale, tar sands, etc.), but also agricultural products and municipal waste, wood and varied biomass. More importantly, it can also be made from chemical recycling of carbon dioxide. Initially the major source will be the CO2 rich flue gases of fossil fuel burning power plants or exhaust of cement and other factories. In the longer range however, considering diminishing fossil fuel resources and the effect of their utilization on earth's atmosphere, even the low concentration of atmospheric CO2 itself could be captured and recycled via methanol, thus supplementing nature’s own photosynthetic cycle. Efficient new absorbents to capture atmospheric CO2 are being developed, mimicking plant life’s ability. Chemical recycling of CO2 to new fuels and materials could thus become feasible, making them renewable on the human timescale.
One m3 of methanol at ambient pressure and temperature contains 1.660 Nm3 of hydrogen (H2) compared to liquid hydrogen; one m3 of liquid hydrogen (LH2) at -253°C contains 788 Nm3 of hydrogen (H2)[6])

ENERGY CRISIS-WIKIPEDIA REPORTS

An energy crisis is any great bottleneck (or price rise) in the supply of energy resources to an economy. In popular literature though, it often refers to one of the energy sources used at a certain time and place. Energy runs machinery in factories, lights our cities and powers our vehicles. There has been an enormous increase in the demand for energy as a result of industrial development and population growth. Supply of energy is, therefore, far less than the actual demand.

Causes

Market failure is possible when monopoly manipulation of markets occurs. A crisis can develop due to industrial actions like union organized strikes and government embargoes. The cause may be over-consumption, aging infrastructure, choke point disruption or bottlenecks at oil refineries and port facilities that restrict fuel supply. An emergency may emerge during unusually cold winters due to increased consumption of energy.

Pipeline failures and other accidents may cause minor interruptions to energy supplies. A crisis could possibly emerge after infrastructure damage from severe weather. Attacks by terrorists or militia on important infrastructure are a possible problem for energy consumers, with a successful strike on a Middle East facility potentially causing global shortages. Political events, for example, when governments change due to regime change, monarchy collapse, military occupation, andcoup may disrupt oil and gas production and create shortages.



Social and economic effects

The macroeconomic implications of a supply shock-induced energy crisis are large, because energy is the resource used to exploit all other resources. When energy markets fail, an energy shortage develops. Electricity consumers may experience intentionally engineered rolling blackouts which are released during periods of insufficient supply or unexpected power outages, regardless of the cause.

Industrialized nations are dependent on oil, and efforts to restrict the supply of oil would have an adverse effect on the economies of oil producers. For the consumer, the price of natural gas, gasoline (petrol) and diesel for cars and other vehicles rises. An early response from stakeholders is the call for reports, investigations and commissions into the price of fuels. There are also movements towards the development of more sustainable urban infrastructure.

In 2006, US survey respondents were willing to pay more for a plug-in hybrid car

In the market, new technology and energy efficiency measures become desirable for consumers seeking to decrease transport costs.[9] Examples include:

Other responses include the development of unconventional oil sources such as synthetic fuel from places like theAthabasca Oil Sands, more renewable energy commercialization and use of alternative propulsion. There may be aRelocation trend towards local foods and possibly microgeneration, solar thermal collectors and other green energysources.

Tourism trends change and ownership of gas-guzzlers vary, both because of increases to fuel costs which are passed on to customers. Items which were not so popular gain favour, such as nuclear power plants and the blanket sleeper, a garment to keep children warm. Building construction techniques change to reduce heating costs, potentially through increased insulation.

[edit]Crisis management

An electricity shortage is felt most by those who depend on electricity for their heating, cooking and water supply. In these circumstances a sustained energy crisis may become a humanitarian crisis.

If an energy shortage is prolonged a crisis management phase is enforced by authorities. Energy audits may be conducted to monitor usage. Various curfews with the intention of increasing energy conservation may be initiated to reduce consumption. To conserve power during the Central Asia energy crisis, authorities in Tajikistan ordered bars and cafes to operate by candlelight.[10] Warnings issued that peak demand power supply might not be sustained.

In the worst kind of energy crisis energy rationing and fuel rationing may be incurred. Panic buying may beset outlets as awareness of shortages spread. Facilities close down to save on heating oil; and factories cut production and lay off workers. The risk of stagflation increases.


Future and alternative energy sources

In response to the petroleum crisis, the principles of green energy and sustainable living movements gain popularity. This has led to increasing interest in alternate power/fuel research such as fuel cell technology, liquid nitrogen economy, hydrogen fuel, methanol, biodiesel, Karrick process, solar energy, geothermal energy, tidal energy, wave power, and wind energy, and fusion power. To date, only hydroelectricity and nuclear power have been significant alternatives to fossil fuel.

Hydrogen gas is currently produced at a net energy loss from natural gas, which is also experiencing declining production in North America and elsewhere. When not produced from natural gas, hydrogen still needs another source of energy to create it, also at a loss during the process. This has led to hydrogen being regarded as a 'carrier' of energy, like electricity, rather than a 'source'. The unproven dehydrogenating process has also been suggested for the use water as an energy source.

Efficiency mechanisms such as Negawatt power can encourage significantly more effective use of current generating capacity. It is a term used to describe the trading of increased efficiency, using consumption efficiency to increase available market supply rather than by increasing plant generation capacity. As such, it is ademand-side as opposed to a supply-side measure.